The theoretical prediction of the standard partial molar volume of the alkyl chains of amino acids in aqueous sodium carboxylate solutions 氨基酸側鏈在羧酸鈉水溶液中標準偏摩爾體積的理論預測
An improved hard - sphere model predicted rightly the changing trend of the standard partial molar volume of alkyl chain of amino acids with concentration of electrolyte , and confirmed the assumption that the sum of standard partial molar volumes of ch and ch3 groups is twice as many as the standard partial molar volume of ch2 group 摘要根據改進的硬球混合物模型,正確預測了氨基酸分子的烴鏈在電解質水溶液中的標準偏摩爾體積隨電解質濃度的變化關系,并證實了“氨基酸分子中ch和ch3基團的標準偏摩爾體積之和是ch2基團標準偏摩爾體積的2倍”這一假定。